Stability of methane clathrate hydrates under pressure: Influence on outgassing processes of methane on Titan     

Mathieu Choukroun  Olivier Grasset 《Icarus》2010,205(2):581-10437

We have conducted high-pressure experiments in the H₂O-CH₄ and H₂O-CH₄-NH₃ systems in order to investigate the stability of methane clathrate hydrates, with an optical sapphire-anvil cell coupled to a Raman spectrometer for sample characterization. The results obtained confirm that three factors determine the stability of methane clathrate hydrates: (1) the bulk methane content of the samples; (2) the presence of additional gas compounds such as nitrogen; (3) the concentration of ammonia in the aqueous solution. We show that ammonia has a strong effect on the stability of methane clathrates. For example, a 10 wt.% NH₃ solution decreases the dissociation temperature of methane clathrates by 14-25 K at pressures above 5 MPa. Then, we apply these new results to Titan’s conditions. Dissociation of methane clathrate hydrates and subsequent outgassing can only occur in Titan’s icy crust, in presence of locally large amounts of ammonia and in a warm context. We propose a model of cryomagma chamber within the crust that provides the required conditions for methane outgassing: emplacement of an ice plume triggers the melting (if solid) or heating (if liquid) of large ammonia-water pockets trapped at shallow depth, and the generated cryomagmas dissociate surrounding methane clathrate hydrates. We show that this model may allow for the outgassing of significant amounts of methane, which would be sufficient to maintain the presence of methane in Titan’s atmosphere for several tens of thousands of years after a large cryovolcanic event.  相似文献   

The petrologic evolution and pre-eruptive conditions of the rhyolitic Kos Plateau Tuff (Aegean arc)   总被引：2，自引：0，他引：2  

Olivier Bachmann 《Central European Journal of Geosciences》2010,2(3):270-305

The Kos Plateau Tuff is a large (>60 km³) and young (160 k.y.) calc-alkaline, high-SiO₂ rhyolitic ignimbrite from the active Kos-Nisyros volcanic center in the Aegean arc (Greece). Combined textural, petrological and geochemical information suggest that (1) the system evolved dominantly by crystal fractionation from (mostly unerupted) more mafic parents, (2) the magma chamber grew over ≥ 250 000 years at shallow depth (～1.5-2.5 kb) and was stored as a H₂O-rich crystalline mush close to its solidus (～670-750°C), (3) the eruption occurred after a reheating event triggered by the intrusion of hydrous mafic magma at the base of the rhyolitic mush. Rare banded pumices indicate that the mafic magma only mingled with a trivial portion of resident crystal-rich rhyolite; most of the mush was remobilized following partial melting of quartz and feldspars induced by advection of heat and volatiles from the underplated, hotter mafic influx.  相似文献   

The recording of floods and earthquakes in Lake Chichój,Guatemala during the twentieth century     

Gilles Brocard  Thierry Adatte  Olivier Magand  Hans-Rudolf Pfeifer  Albedo Bettini  Fabien Arnaud  Flavio S. Anselmetti  Sergio Moran-Ical 《Journal of Paleolimnology》2014,52(3):155-169

Laguna Chichój (Lake Chichój) is the only deep permanent lake in the central highlands of Guatemala. The lake is located in the boundary zone between the North American and Caribbean plates. The lake has been struck by devastating earthquakes and tropical cyclones in historical times. We investigated the imprint of twentieth century extreme events on the sedimentary record of this tropical lake using a bathymetric survey of the lake, coring the lake floor, and providing a chronology of sediment accumulation. The lake occupies a series of circular depressions likely formed by the rapid dissolution of a buried body of gypsum. ²¹⁰Pb and ¹³⁷Cs inventories and varve counting indicate high rates of sedimentation (1–2 cm year^?1). The annually layered sediment is interrupted by turbidites of two types: a darker-colored turbidite, enriched in lake-derived biogenic constituents, and interpreted as a seismite, and a lighter-colored type, enriched in catchment-derived constituents, interpreted as a flood layer. Comparison of our ¹³⁷Cs-determined layer ages with a catalog of twentieth century earthquakes shows that an earthquake on the Motagua fault in 1976 generated a conspicuous darker-colored turbidite and slumped deposits in separate parts of the lake. The entire earthquake inventory further reveals that mass movements in the lake are triggered at Modified Mercalli Intensities higher than V. Tropical cyclonic depressions known to have affected the lake area had limited effect on the lake, including Hurricane Mitch in 1998. One storm however produced a significantly thicker flood layer in the 1940s. This storm is reportedly the only event to have generated widespread slope failures in the lake catchment. It is thus inferred that abundant landsliding provided large amounts of concentrated sediment to the lake, through hyperpycnal flows.  相似文献   

Effect of the processing methodology on satellite altimetry-based global mean sea level rise over the Jason-1 operating period     

Olivier Henry  Michael Ablain  Benoit Meyssignac  Anny Cazenave  Dallas Masters  Steve Nerem  Gilles Garric 《Journal of Geodesy》2014,88(4):351-361

Determining how the global mean sea level (GMSL) evolves with time is of primary importance to understand one of the main consequences of global warming and its potential impact on populations living near coasts or in low-lying islands. Five groups are routinely providing satellite altimetry-based estimates of the GMSL over the altimetry era (since late 1992). Because each group developed its own approach to compute the GMSL time series, this leads to some differences in the GMSL interannual variability and linear trend. While over the whole high-precision altimetry time span (1993–2012), good agreement is noticed for the computed GMSL linear trend (of $3.1\pm 0.4$  mm/year), on shorter time spans (e.g., ${<}10~\hbox {years}$ ), trend differences are significantly larger than the 0.4 mm/year uncertainty. Here we investigate the sources of the trend differences, focusing on the averaging methods used to generate the GMSL. For that purpose, we consider outputs from two different groups: the Colorado University (CU) and Archiving, Validation and Interpretation of Satellite Oceanographic Data (AVISO) because associated processing of each group is largely representative of all other groups. For this investigation, we use the high-resolution MERCATOR ocean circulation model with data assimilation (version Glorys2-v1) and compute synthetic sea surface height (SSH) data by interpolating the model grids at the time and location of “true” along-track satellite altimetry measurements, focusing on the Jason-1 operating period (i.e., 2002–2009). These synthetic SSH data are then treated as “real” altimetry measurements, allowing us to test the different averaging methods used by the two processing groups for computing the GMSL: (1) averaging along-track altimetry data (as done by CU) or (2) gridding the along-track data into $2^{\circ }\times 2^{\circ }$ meshes and then geographical averaging of the gridded data (as done by AVISO). We also investigate the effect of considering or not SSH data at shallow depths $({<}120~\hbox {m})$ as well as the editing procedure. We find that the main difference comes from the averaging method with significant differences depending on latitude. In the tropics, the $2^{\circ }\times 2^{\circ }$ gridding method used by AVISO overestimates by 11 % the GMSL trend. At high latitudes (above $60^{\circ }\hbox {N}/\hbox {S}$ ), both methods underestimate the GMSL trend. Our calculation shows that the CU method (along-track averaging) and AVISO gridding process underestimate the trend in high latitudes of the northern hemisphere by 0.9 and 1.2 mm/year, respectively. While we were able to attribute the AVISO trend overestimation in the tropics to grid cells with too few data, the cause of underestimation at high latitudes remains unclear and needs further investigation.  相似文献   

Soil treatment with organic non-traditional additives for the improvement of earthworks   总被引：2，自引：0，他引：2  

Gaëtan Blanck  Olivier Cuisinier  Farimah Masrouri 《Acta Geotechnica》2014,9(6):1111-1122

The aim of this study was to characterise the technical and environmental implications of non-traditional treatments of a low-plasticity compacted silt (PI = 14) and to investigate their actions both at the micro- and macro-structural scales. Three non-traditional additives derived from industrial vegetal by-products were studied. These additives are classified as an acid solution, an enzymatic solution (ES) and calcium lignosulfonate (LS). The first step was to characterise the effects of these treatments on Proctor compaction, bearing capacity, unconfined compressive strength and stiffness. The index properties of the treated samples were also measured to assess changes in the interaction between soil minerals and the additives. These experimental results showed that the 0.002 % ES and 2.0 % LS treatments were the most effective at improving the soil dry density and allowing the soil to reach optimum density using 3 % less water or 25 % less compaction energy. In a second step, the mechanisms involved in the treatment were investigated. A microscopic study was conducted including scanning electron microscopy and mercury injection porosity tests; measurements of the surface tension of non-traditional additives mixed with water completed the study and demonstrated that the ES treatment has the same surfactant properties as sodium dodecyl sulphate, a common surfactant. Compaction tests confirmed that the behaviours of the soil after ES and sodium dodecyl sulphate treatments were similar.  相似文献   

Origin and significance of poikilitic and mosaic peridotite xenoliths in the western Pannonian Basin: geochemical and petrological evidences     

Antal?Embey-IsztinEmail author  Gábor?Dobosi  Jean-Louis?Bodinier  Delphine?Bosch  G.?A.?Jenner  Simone?Pourtales  Olivier?Bruguier 《Contributions to Mineralogy and Petrology》2014,168(3):1054

Peridotite xenoliths erupted by alkali basaltic volcanoes in the western Pannonian Basin can be divided into two fundamentally contrasting groups. Geochemical characteristics of the abundant protogranular, porphyroclastic and equigranular nodules suggest that these samples originate from an old consolidated and moderately depleted lithospheric mantle domain. In contrast, the geochemical features of the worldwide rare, but in the Pannonian Basin relatively abundant, poikilitic xenoliths attest to a more complex evolution. It has been argued that the origin of the peculiar texture and chemistry may be intimately linked to melt/rock reactions at successively decreasing liquid volumes in a porous melt flow system. The most likely site where such reactions can take place is the asthenosphere–lithosphere boundary. In this context, poikilitic xenoliths may provide petrological and geochemical evidence for reactions between magmatic liquids issued from the uprising asthenosphere and the solid mantle rocks of the lithosphere. These reactions are important agents of the thermal erosion of the lithosphere; thus, they could have considerably contributed to the thinning of the lithosphere in the Pannonian region. We suggest that in the Pannonian Basin, there could be a strong relation between the unusual abundance of poikilitic mantle xenoliths and the strongly eroded lithosphere.  相似文献   

Deciphering petrogenic processes using Pb isotope ratios from time-series samples at Bezymianny and Klyuchevskoy volcanoes,Central Kamchatka Depression     

Theresa?M.?KayzarEmail author  Bruce?K.?Nelson  Olivier?Bachmann  Ann?M.?Bauer  Pavel?E.?Izbekov 《Contributions to Mineralogy and Petrology》2014,168(4):1067

The Klyuchevskoy group of volcanoes in the Kamchatka arc erupts compositionally diverse magmas (high-Mg basalts to dacites) over small spatial scales. New high-precision Pb isotope data from modern juvenile (1956–present) erupted products and hosted enclaves and xenoliths from Bezymianny volcano reveal that Bezymianny and Klyuchevskoy volcanoes, separated by only 9 km, undergo varying degrees of crustal processing through independent crustal columns. Lead isotope compositions of Klyuchevskoy basalts–basaltic andesites are more radiogenic than Bezymianny andesites (²⁰⁸Pb/²⁰⁴Pb = 37.850–37.903, ²⁰⁷Pb/²⁰⁴Pb = 15.468–15.480, and ²⁰⁶Pb/²⁰⁴Pb = 18.249–18.278 at Bezymianny; ²⁰⁸Pb/²⁰⁴Pb = 37.907–37.949, ²⁰⁷Pb/²⁰⁴Pb = 15.478–15.487, and ²⁰⁶Pb/²⁰⁴Pb = 18.289–18.305 at Klyuchevskoy). A mid-crustal xenolith with a crystallization pressure of 5.2 ± 0.6 kbars inferred from two-pyroxene geobarometry and basaltic andesite enclaves from Bezymianny record less radiogenic Pb isotope compositions than their host magmas. Hence, assimilation of such lithologies in the middle or lower crust can explain the Pb isotope data in Bezymianny andesites, although a component of magma mixing with less radiogenic mafic recharge magmas and possible mantle heterogeneity cannot be excluded. Lead isotope compositions for the Klyuchevskoy Group are less radiogenic than other arc segments (Karymsky—Eastern Volcanic Zone; Shiveluch—Northern Central Kamchatka Depression), which indicate increased lower-crustal assimilation beneath the Klyuchevskoy Group. Decadal timescale Pb isotope variations at Klyuchevskoy demonstrate rapid changes in the magnitude of assimilation at a volcanic center. Lead isotope data coupled with trace element data reflect the influence of crustal processes on magma compositions even in thin mafic volcanic arcs.  相似文献   

Building zoned ignimbrites by recycling silicic cumulates: insight from the 1,000 km<Superscript>3</Superscript> Carpenter Ridge Tuff,CO     

Olivier?BachmannEmail author  Chad?D.?Deering  Peter?W.?Lipman  Charles?Plummer 《Contributions to Mineralogy and Petrology》2014,167(6):1025

The ~1,000 km³ Carpenter Ridge Tuff (CRT), erupted at 27.55 Ma during the mid-tertiary ignimbrite flare-up in the western USA, is among the largest known strongly zoned ash-flow tuffs. It consists primarily of densely welded crystal-poor rhyolite with a pronounced, highly evolved chemical signature (high Rb/Sr, low Ba, Zr, Eu), but thickly ponded intracaldera CRT is capped by a more crystal-rich, less silicic facies. In the outflow ignimbrite, this upper zone is defined mainly by densely welded crystal-rich juvenile clasts of trachydacite composition, with higher Fe–Ti oxide temperatures, and is characterized by extremely high Ba (to 7,500 ppm), Zr, Sr, and positive Eu anomalies. Rare mafic clasts (51–53 wt% SiO₂) with Ba contents to 4,000–5,000 ppm and positive Eu anomalies are also present. Much of the major and trace-element variations in the CRT juvenile clasts can be reproduced via in situ differentiation by interstitial melt extraction from a crystal-rich, upper-crustal mush zone, with the trachydacite, crystal-rich clasts representing the remobilized crystal cumulate left behind by the melt extraction process. Late recharge events, represented by the rare mafic clasts and high-Al amphiboles in some samples, mixed in with parts of the crystal cumulate and generated additional scatter in the whole-rock data. Recharge was important in thermally remobilizing the silicic crystal cumulate by partially melting the near-solidus phases, as supported by: (1) ubiquitous wormy/sieve textures and reverse zoning patterns in feldspars and biotites, (2) absence of quartz in this very silicic unit stored at depths of >4–5 km, and (3) heterogeneous melt compositions in the trachydacite fiamme and mafic clasts, particularly in Ba, indicating local enrichment of this element due mostly to sanidine and biotite melting. The injection of hot, juvenile magma into the upper-crustal cumulate also imparted the observed thermal gradient to the deposits and the mixing overprint that partly masks the in situ differentiation process. The CRT provides a particularly clear perspective on processes of in situ crystal-liquid separation into a lower crystal-rich zone and an upper eruptible cap, which appears common in incrementally built upper-crustal magma reservoirs of high-flux magmatic provinces.  相似文献   

Warm‐temperate,marine, carbonate sedimentation in an Early Miocene,tide‐influenced,incised valley; Provence,south‐east France     

Noel P. James  Margaret J. Seibel  Robert W. Dalrymple  David Besson  Olivier Parize 《Sedimentology》2014,61(2):497-534

The Saumane‐Venasque compound palaeovalley succession accumulated in a strongly tide‐influenced embayment or estuary. Warm‐temperate normal marine to brackish conditions led to deposition of extensive cross‐bedded biofragmental calcarenites. Echinoids, bryozoans, coralline algae, barnacles and benthic foraminifera were produced in seagrass meadows, on rocky substrates colonized by macroalgae and within subaqueous dune fields. There are two sequences, S1 and S2, the first of which contains three high‐frequency sequences (S1a, S1b and S1c). Sequence 1 is largely confined to the palaeovalley with its upper part covering interfluves. Each of these has a similar upward succession of deposits that includes: (i) a basal erosional surface that is bored and glauconitized; (ii) a discontinuous lagoonal lime mudstone or wackestone; (iii) a thin conglomerate generated by tidal ravinement; (iv) a transgressive systems tract series of cross‐bedded calcarenites; (v) a maximum flooding interval of argillaceous, muddy quartzose, open‐marine limestones; and (vi) a thin highstand systems tract of fine‐grained calcarenite. Tidal currents during stages S1a, S1b and S1c were accentuated by the constricted valley topography, whereas basin‐scale factors enhanced tidal currents during the deposition of S2. The upper part of the succession in all but S1c has been removed by later erosion. There is an overall upward temporal change with quartz, barnacles, encrusting corallines and epifaunal echinoids decreasing but bryozoans, articulated corallines and infaunal echinoids increasing. This trend is interpreted to be the result of changing oceanographic conditions as the valley was filled, bathymetric relief was reduced, rocky substrates were replaced as carbonate factories by seagrass meadows and subaqueous dunes, and the setting became progressively less confined and more open marine. These limestones are characteristic of a suite of similar cool‐water calcareous sand bodies in environments with little siliciclastic or fresh water input during times of high‐amplitude sea‐level change wherein complex inboard antecedent topography was flooded by a rising ocean.  相似文献   

Contribution of climatic and anthropogenic effects to the hydric deficit of peatlands     

Chrystelle Auterives  Luc Aquilina  Olivier Bour  Mélanie Davranche  Valérie Paquereau 《水文研究》2011,25(18):2890-2906

The present study makes use of a detailed water balance to investigate the hydrological status of a peatland with a basal clay‐rich layer overlying an aquifer exploited for drinking water. The aim is to determine the influence of climate and groundwater extraction on the water balance and water levels in the peatland. During the two‐year period of monitoring, the hydrological functioning of the wetland showed a hydric deficit, associated with a permanent unsaturated layer and a deep water table. At the same time, a stream was observed serving as a recharge inflow instead of draining the peatland, as usually described in natural systems. Such conditions are not favourable for peat accumulation. Field investigations show that the clay layer has a high hydraulic conductivity (from 1·10^?7 to 3·10^?9 m.s^?1) and does not form a hydraulic barrier. Moreover, the vertical hydraulic gradients are downward between the peat and the sand aquifer, leading to high flows of groundwater through the clay layer (20–48% of the precipitation). The observed hydric deficit of the peatland results from a combination of dry climatic conditions during the study period and groundwater extraction. The climatic effect is mainly expressed through drying out of the peatland, while the anthropogenic effect leads to an enhancement of the climatic effect on a global scale, and a modification of fluxes at a local scale. The drying out of the peatland can lead to its mineralisation, which thus gives rise to environmental impacts. The protection of such wetlands in the context of climate change should take account of anthropogenic pressures by considering the wetland‐aquifer interaction. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献